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Zinc and its alloys are considered as promising materials for the preparation of biodegradable medical devices (stents and bone fixation screws) due to their enhanced biocompatibility. The corresponding corrosion mechanism of porous zinc was also discussed. The corrosion rate of the porous zinc obtained through an immersion test in vitro using simulated bodily fluids on the thirty-second day was close to 0.02 mm/year. The porous zinc prepared with FBCP showed the highest compressive strength and elastic modulus. A fluctuated stress plateau could be found due to the brittle fracture of the porous cells. Moreover, a compression test and immersion test were performed to investigate the stress–strain behavior and corrosion properties of the resulting porous zinc. The porosity of the porous zinc increased with the stirring time, the content of protein and sucrose, and higher sintering temperatures. Compared to the porous zinc prepared with EWP or BBCP, the porous zinc prepared with FBCP possessed the largest average pore size and the highest compressive properties. The morphological characteristics of the pore structures revealed that the porous zinc had an interconnected open-cell structure. The preparation route utilized powder mixing and sintering processing, which could be divided into three steps: slurry preparation, low-temperature foaming, and high-temperature sintering. These data indicate that the proposed non-uniform degradation model of BVSs with multiple factors produces different phenomena compared with the commonly used models and make the numerical simulation results more consistent with the real degradation scenario.Ī new protein foaming–consolidation method for preparing porous zinc was developed using three proteins (egg white protein (EWP), bovine bone collagen protein (BBCP), and fish bone collagen protein (FBCP)) as both consolidating and foaming agents. The effective support of the stent to the vessel could reach at least 60% of the treatment effect before the vessel collapsed. The addition of the pitting model reduces the service life of the BVSs by up to 12%. The results revealed that adjusting the corrosion rate according to the number of exposed surfaces of the element and reducing the stress threshold according to the corrosion status accelerates the degradation time of BVSs by 26% and 25%, respectively, compared with the uniform degradation model. ![]() This paper aims to establish an FEA model for the non-uniform degradation of BVSs by considering factors such as the dynamic changes of the corrosion properties and material properties of the element, as well as the pitting corrosion and stress corrosion. Most of the studies on the finite element analysis (FEA) of biodegradable vascular stents (BVSs) during the degradation process have limited the accuracy of the simulation results due to the application of the uniform degradation model. This article seeks to offer a review of related research progress on Zn-based biodegradable materials, which may provide a useful reference for future studies on Zn-based biodegradable materials targeting applications in orthopedic internal fixation. Emerging Zn-based alloys and composites have been developed in recent years and in vitro and in vivo studies have been performed to explore their biodegradability, mechanical property, and biocompatibility in order to move towards the ultimate goal of clinical application in fracture fixation. Zn alloys have comparable mechanical properties with traditional metal materials, e.g., titanium (Ti), and have a moderate degradation rate, potentially serving as a good candidate for internal fixation materials, especially at load-bearing sites of the skeleton. However, the issues with an over-fast degradation rate and release of hydrogen still need to be overcome. During the last decades, Mg-based alloys have attracted much attention by researchers. Biodegradable materials, such as magnesium (Mg)-, iron (Fe)- and zinc (Zn)-based alloys, open up a new pathway to address those issues. Traditional inert materials used in internal fixation have caused many complications and generally require removal with secondary surgeries. ![]() ![]() ![]()
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Here are some test and example programs, ready to compile with the libaries and write to flash: Here is a PWM controller project for a motor: Here is a water tank level sensor using ultrasonic rangefinder: Feel free to browse the code, and use whatever you like. It also has a support library for the STM8S003 W1209 thermostat, which has three buttons, a 3-digit display, a temperature probe, and a relay. The libraries have support for many input and output devices, such as keypads, LCD, and LED modules, binary/decimal conversion, PWM/servo control, ultrasonic rangefinding, UART. Most of it is for STM8S103 or STM8S105, but the STM8S003 is so close, they will work fine. I have a nice ecosystem of STM8 libraries, sample/example programs, and projects on github. I use the free SDCC (small device C compiler) and ST-LINK V2 and stm8flash to program the chips. ![]() |
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